| SL | Name | Period |
| 1 | Sri. W.T.A. Cosby, Barrister-at-Law | 1894–1900 |
| 2 | Sri. E.J.R.V. Hunt, Barrister-at-Law | 1900–1914 |
| 3 | Sri. H.S. Chatfield, M.A., Barrister-at-Law | 1915–1926 |
| 4 | Sri. E.J. John, B.A., B.L | 1926–1931 |
| 5 | Sri. Malloor K. Govinda Pillai, B.A., B.L | 1931–1933 |
| 6 | Sri. E. Subramonia Iyer, M.A., B.L | 1933–1937 |
| 7 | Sri. K.P. Padmanabha Pillai, B.A. (Barrister-at-Law) | 1937–1944 |
| 8 | Sri. K. Narayanan, B.A., B.L | 1944–1954 |
| 9 | Prof. V.N. Subramoniyaiyer, M.A., M.L | 1954–1958 |
| 10 | Prof. P.S. Achuthan Pillai, M.A., M.L | 1958–1960 |
| 11 | Prof. V.N. Subramoniya Iyer, M.A., M.L | 1960–1961 |
| 12 | Prof. R. Sankaradasan Thampi, B.Sc., M.L | 1961–1963 |
| 13 | Prof. (Dr.) A.T. Markose, M.A., M.L., LL.D | 1963 (February to June) |
| 14 | Prof. R. Sankaradasan Thampi, B.Sc., M.L | 1963–1967 |
| 15 | Prof. Philip K. Thayyil, B.A., B.L | 1967–1973 |
| 16 | Prof. M. Krishnan Nair, M.A., M.L., LL.M | 1973–1979 |
| 17 | Prof. K. Sreekantan, B.Sc., M.L | 1979–1981 |
| 18 | Prof. Jose T. Manjooran, B.A., M.L | 1981–1987 |
| 19 | Prof. K. Nadarajan, B.A., M.L | 1987–1990 |
| 20 | Prof. V. Vijaya Balan, B.Sc., M.L | 1990–1994 |
| 21 | Prof. V.L. Charlotte, B.Sc., M.L | 1994–1996 |
| 22 | Prof. Pauline Rose Mathai, B.A., M.L | 1996–1997 |
| 23 | Prof. K.V. Narayanikutty, B.A., M.L | 1997–1999 |
| 24 | Prof. P.J. Grace, B.A., M.L | 1999–2000 |
| 25 | Prof. K.V. Narayanikutty, B.A., M.L | 2000–2001 |
| 26 | Prof. L. Rita, B.A., LL.M | 2002–2003 |
| 27 | Prof. A. Sathyaseelan, B.Sc., LL.M | 2003–2005 |
| 28 | Prof. P.P. Paul, B.Sc., LL.M | 2005–2007 |
| 29 | Prof. S. Anujan, B.A., LL.M | 2007–2008 |
| 30 | Prof. (Dr.) S.S. Salini, B.Sc., LL.M., Ph.D | 2008–2009 |
| 31 | Prof. S. Usha, B.A., LL.M | 2009–2010 |
| 32 | Prof. (Dr.) G. Rajasekharan Nair, B.Sc., LL.M., Ph.D | 2010–2011 |
| 33 | Prof. (Dr.) Saroja A.S., B.Sc., LL.M., Ph.D | 2011–2014 |
| 34 | Prof. (Dr.) Lovely Paulose, B.Sc., LL.M., Ph.D | 2014–2015 |
| 35 | Dr. R. Biju Kumar, B.Sc., LL.M., Ph.D | 2015–2017 |
| 36 | Dr. Reghunathan K.R., LL.M., Ph.D | 2017–2019 |
| 37 | Dr. Agitha T.G., B.Sc., LL.M., Ph.D | 2019–2020 |
| 38 | Prof. (Dr.) Bindu M. Nambiar, LL.M., Ph.D | 2020–2025 |
| 39 | Dr. Mini Paul, LL.M., Ph.D | 2025 (June to December) |
| 40 | Prof. (Dr.) Bindumol V.C., LL.M., Ph.D | 2025– |